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It is widely acknowledged that the CFR octane rating engines are not representative of modern engines and that there is a gap in the quantification of knock severity between the two engine types. As part of a comprehensive study of the autoignition of different fuels in both the CFR octane rating engines and a modern, direct injection, turbocharged spark-ignited engine, a series of fuel blends were tested with varying composition, octane numbers and ethanol blend levels. The paper reports on the fourth part of this study where cylinder pressures were recorded under standard knock conditions in CFR engines under RON and MON conditions using the ASTM prescribed instrumentation. By the appropriate signal conditioning of the D1 detonation pickups on the CFR engines, a quantification of the knock severity was possible that had the same frequency response as a cylinder pressure transducer.

Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.

Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.

Despite considerable progress over the last several decades, California continues to face some of the most significant air quality problems in the United States. These continued issues highlight the need for further mobile source NOX reductions to help California and other areas meet ambient air quality targets mandated by the U.S. EPA. Beginning in 2014, the California Air Resources Board (CARB) launched a program aimed at demonstrating technologies that could enable heavy-duty on-highway engines to reach tailpipe NOX levels up to 90% below the current standards, which were implemented in 2010. At the same time, mandated improvements to greenhouse gas emissions (GHG) require that these NOX reductions be achieved without sacrificing fuel consumption and increasing GHG emissions.

With the conclusion of the California Air Resources Board (CARB) Stage 1 Ultra-Low NOX (ULN) program, there continues to be a commitment for identifying potential pathways to demonstrate 0.02 g/bhp-hr NOX emissions. The Stage 1 program focused on achieving the ULN levels on the heavy-duty regulatory cycles utilizing a turbo-compound engine which required the integration of novel catalyst technologies and a supplemental heat source. While the aftertreatment configuration provided a potential solution to meet the ULN target, a complicated approach with a greenhouse gas (GHG) penalty was required to overcome challenges from low temperature exhaust. A subsequent Stage 2 program was concerned with the development of a new low load test cycle and evaluating the trade-off between GHG and tailpipe NOX on the Stage 1 ULN solution.

The current operation of the International Space Station (ISS) calls for the oxygen used by the occupants to be vented overboard in the form of CO2, after the CO2 is scrubbed from the cabin air. Likewise, H2 produced via electrolysis in the oxygen generator is also vented. NASA is investigating the use of the Sabatier process to combine these two product streams to form water and methane. The water is then used in the oxygen generator, thereby conserving this valuable resource. One of the technical challenges to developing the Sabatier reactor is transferring CO2 from the Carbon Dioxide Removal Assembly (CDRA) to the Sabatier reactor at the required rate, even though the CDRA and the Sabatier reactor operate on different schedules. One possible way to transfer and store CO2 is to use a mechanical compressor and a storage tank.

Automotive catalytic converters must provide a very high level of mechanical and thermal durability to maintain performance during their 100,000 to 150,000 mile life expectancy. The work reported herein characterizes the converter as a base (can) excited spring (mat material) supported mass (substrate). A mat material coupon test apparatus was developed for the purpose of providing parameter data for the converter model in the form of stiffness and material loss factor data as a function of shear deflection across the mat. An intumescent mat material was chosen and its dynamic properties evaluated for a range of converter operating parameters. The mat material response properties were placed into a mat material database as a function of gap bulk density, substrate temperature, and temperature gradient across the mat.

To aid in the catalytic converter design and development process, a test apparatus was designed and built which will allow comparative evaluation of the durability of candidate mat materials under highly controlled thermal and vibration environments. The apparatus directly controls relative shear deflection between the substrate and can to impose known levels of mat material strain while recording the transmitted shear force across the mat material. Substrate and can temperatures are controlled at constant levels using a resistive thermal exposure (RTE) technique. Mat material fatigue after several million cycles is evident by a substantial decrease in the transmitted force. A fragility test was found to be an excellent method to quickly compare candidate materials to be used for a specific application. Examples of test results from several materials are given to show the utility of the mat material evaluation technique.

An increasing number of passenger vehicle exhaust systems incorporate catalytic converters that are “close-coupled” to the exhaust manifold to further reduce the quantity of cold-start emissions and increase overall catalyst conversion efficiencies. In general, close-coupled catalytic converters are not necessarily subjected to higher inlet exhaust temperatures than conventional underbody catalytic converters. To establish a foundation of on-vehicle temperature data, several passenger vehicles with close-coupled catalytic converters were studied while operating on a chassis dynamometer. Converter temperatures were measured over a variety of vehicle test conditions, including accelerations and extended steady-state speeds for several throttle positions, at both zero- and four-percent simulated road grades.

In order to further reduce vehicle cold-start emissions, the use of catalytic converters that are “close-coupled” to the exhaust manifold is increasing. To understand the vibrational environment of close-coupled and underbody converters, a laboratory study was conducted on several passenger vehicles. Catalytic converter vibration spectra were measured on a chassis dynamometer with the vehicle operating over a variety of test conditions. Vehicle operating conditions included hard accelerations and extended steady-state speeds at distinct throttle positions over zero-percent and four-percent simulated road grades.

To counter the adverse impact on the formation of harmful unregulated emissions such as nitro-polycyclic aromatic hydrocarbons (NPAH), catalyst companies and researchers have been developing catalytic coatings that have the capability of suppressing the formation of NO2. NO2 is formed at low exhaust temperatures with potentially greater concentrations at part load engine operation. Haldor Topsoe, a catalyst company from Denmark, developed such a catalytic coating for DPFs. A sample was provided to Southwest Research Institute (SwRI) to conduct this research with a view of potentially improving NO2-suppressing formulations in the future. The Haldor Topsoe diesel particulate filter (DPF) with its novel coating was tested together with three other DPFs and the results confirmed the capability of this DPF to suppress the formation of NO2. This characteristic was apparent in all five engine test modes selected to cover the full engine operating range.

An electromagnetic valve actuation (EVA) system was developed and applied to a Kohler Command Series engine. Engine development and testing was conducted for the purpose of evaluating the performance of the EVA-equipped engine, running on natural gas, in an engine-test laboratory environment. As part of this effort, a personal computer-based engine control system, which managed the fueling, ignition, throttling, and intake/exhaust valve control functions, was developed. The evaluation included an investigation into increasing engine power output and full load efficiency, as well as increased part load efficiency. Techniques including optimized valve events as a function of operating condition, and throttleless operation using early and late intake valve closing are presented. Engine simulation results are compared with actual engine data and presented in this paper.

The 2010 emission standards for heavy-duty diesel engines in the U.S. have established a limit for oxides of nitrogen (NOx) emissions of 0.20 g/bhp-hr., a 90% reduction from the previous emission standards. However, it has been projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with the 2010 emission standards, the upcoming National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and ozone will not be achieved in California without further significant reductions in NOx emissions from the heavy-duty vehicle fleet. Given this, there is potential of further reduction in NOx emissions limit standards for heavy duty engines in the US. Recently there have been extensive studies and publications focusing on ultra-low NOx after treatment technologies that help achieve up to 0.02g/bhp-hr. at tailpipe [1].

This paper describes the findings of a laboratory effort to demonstrate improved automotive exhaust emission control with a cold-start hydrocarbon collection system. The emission control strategy developed in this study incorporated a zeolite molecular sieve in the exhaust system to collect cold-start hydrocarbons for subsequent release to an active catalytic converter. A prototype emission control system was designed and tested on a gasoline-fueled vehicle. Continuous raw exhaust emission measurements upstream and downstream of the zeolite molecular sieve revealed collection, storage, and release of cold-start hydrocarbons. Federal Test Procedure (FTP) emission results show a 35 percent reduction in hydrocarbons emitted during the cold-transient segment (Bag 1) due to adsorption by the zeolite.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

Modern spark ignited engines face multiple barriers to achieving higher thermal efficiency. This study investigated the potential of utilizing both continuously variable valve actuation (VVA) and low-pressure cooled exhaust gas recirculation (EGR) to improve engine thermal efficiency at part-load conditions. Six speed / load points were investigated on a 1.6 L turbocharged gasoline direct injection engine. A design of experiment (DoE) approach using the Box-Behnken surface response model was conducted. The DoE results revealed different brake specific fuel consumption (BSFC) responses to the valve phasing and the intake valve lift at different operating conditions. Further engine testing was carried out at each speed / load point to confirm the engine efficiency and combustion performance when targeting different valvetrain controls and EGR strategies. The results indicated that utilizing the VVA system could always reduce BSFC at the studied operating conditions.

The abnormal autoignition of the unburned gas, namely knock, at high loads is a major challenge for modern spark ignited engines. Knock prevents the application of high compression ratios due to the increased unburned gas temperature, and it becomes increasingly severe for downsized engines with high specific powers. The current paper reports on the potential of utilizing continuously variable valve actuation (VVA) and low-pressure exhaust gas recirculation (EGR) to reduce knock tendency at high loads. Five speed / load points were investigated on a 1.6 L turbocharged gasoline direct injection engine. The brake specific fuel consumption (BSFC) response to the valve phasing and the intake valve lift was investigated with the design of experiment (DoE) approach. The DoE was conducted using a Box-Behnken surface response model. The results exhibited insensitive response of BSFC to intake valve lift and overlap.

Mixtures of methanol, water and heavier alcohols, simulating “raw’ methanol at various levels of processing, were tested in a constant volume combustion apparatus (CVCA) and in a single-cylinder, direct-injection diesel engine. The ignition characteristics determined in the CVCA indicated that the heavier alcohols have beneficial effects on the auto-ignition quality of the fuels, as compared to pure methanol. Water, at up up to 10 percent by volume, has little effect on the ignition quality. In all cases, however, the cetane numbers of the alcohol mixtures were very low. The same fuels were tested in a single cylinder engine, set-up in a configuration similar to current two-valve DI engines, except that the compression ratio was increased to 19:1. Pure methanol and five different blends of alcohols and water were tested in the engine at five different speed-load conditions.

Comparative abuse tests were performed on commercially available 12 V and 36 V battery designs. Four methods were chosen from SAE J2464 standard, Electrical Vehicle Battery Abuse Testing, March 1999, and modified to apply them to typical-sized automotive batteries. The four tests included a Penetration Test, Crush Test, Radiant Heat Test, and Short Circuit Test. Both the 12 V and 36 V batteries showed minimal reactions to the tests, and there was no significant difference between results of the two designs with respect to the abuse tests performed. It should be stressed however, that this project was limited in scope and was not intended to be a thorough investigation in the batteries safety hazards.

The confluence of increasing fuel economy requirements and increased use of ethanol as a gasoline blend component has led to various studies into the efficiency and performance benefits of higher octane numbers and high ethanol content fuels in modern engines. As part of a comprehensive study of the autoignition of different fuels in both the CFR octane rating engine and a modern, direct injection, turbocharged spark ignited engine, a series of fuel blends were prepared with varying composition, octane numbers and ethanol blend levels. The paper reports on the second part of this study where cylinder pressures were recorded for fuels under knocking conditions in both a single cylinder research engine (SCRE), utilizing a GM LHU head and piston, as well as the CFR engines used for octane ratings.